I have done a ton of research and have memorized just about every location. There is A LOT, in fact most areas can have a random event occur. Out in the wastes (out of the city) is the best place to look, have dogmeat with you. He will be able to find the gun/ammo when the firelance event does occur. There are several things to look for, one thing is to look for a large, green explosion. Although I recommend not relying too much on this because when I found my firelance there was no explosion of green lights or any sound (weird I know). Also you will be surrounded with radiation. BTW the higher your luck the more chance you have at getting the firelance.
So:
1-Get the your luck at a ten
2. Obtain Dogmeat at the scrapyard
3. Just explore. Do not go looking for it because you will be very disappointed, it will most likely take forever. Just explore, play, and pay attention to these signs. Eventually it will happen. I have told you what occurs during the event and things that can increase your chances, trust me...do not look for it. Just forget about it and be surprised when it occurs.
Now that I think about it I never tried out my Firelance (not even once). *Runs off to go play fallout 3*
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