Brawl compresses all it's data into .bin files. If you open them up in a archieving program like PowerArchiever, you won't get anything. To actually see the pictures, go to this SSBB decrypter page. Just copy the .bin file from your SD card into a folder, browse for the folder on the site, click on the .bin file, hit the "Decrypt" button, and save the picture to your computer.
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