Man I can't wait till the PS3 really starts rolling out some RPG's.
Star Ocean 4
The Last Remnant (multi-plat, but still sweet)
FFXIII: Fabula Nova Crystallis Compilation
Kingdom Hearts 3 (will almost undoubtedly be on the PS3)
White Knight Chronicles
These are all I can think of at the moment. But there are many more I'm sure. Once the PS3 gets off this FPS Drug overdose it's in right now, we'll finally be able to enjoy some quality RPG's. Just the thought of 2 more FF's after XIII gets me all worked up(and yes, there will almost certainly be 2 if not more FF's before the PS3's life cycle is up. The PS1 had 3, the PS2 had three. I'm pretty sure the PS3 will follow suit.