Depends entirely on your build and how you like to play. I don't use shields, instead I left-hand a rapier which is very fast, pierces shields, and has a parry strong-attack. Rapiers and curved swords will be your choice weapons if you want speed. You can get the Espada Ropera by talking to Chancellor Wellager after defeating the Giant Lord. He'll also give you the Royal Dirk which has a 150 physical damage base, fully upgraded, and additional poison.
Whips are also a good off-hand or switch-to weapon, especially the Spotted Whip obtained from Straid in exchange for the Demon of Song soul. Twinblades are also great - they're fast and they deal heavy bleed damage. The Warped Sword you also get from Straid for the Flexile Sentry soul is another good curved blade, as is the Manikin Sabre.
As for katanas, your best bet is the Manslayer - decent damage and poison build-up. I infused my Manslayer with a poison stone to increase the poisoning potential. If you're really dedicated you can try for the Berserker Blade in Belfry Sol, though it's a very rare drop and might require hours of grinding a Black Phantom who only spawns 20% of the time. But it's hands down the quickest of the katanas and deals the most damage, aside from the Washing Pole.
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